Vanuatu norbornadiene solar energy storage
Engineering of Norbornadiene/Quadricyclane
ConspectusRenewable energy resources are mostly intermittent and not evenly distributed geographically; for this reason, the development of new technologies for energy storage is in high demand.Molecules that undergo
Front Cover: Push‐Pull Bis‐Norbornadienes for Solar Thermal Energy
The norbornadiene derivatives designed and studied in this work swirl around the flask like autumn leaves symbolizing the cyclic nature of molecular solar thermal energy storage; and as leaves turn red in autumn, so the absorption of these
Solar Energy Storage by Molecular Norbornadiene
Here, norbornadiene (NBD)–quadricyclane (QC) molecular photoswitches are embedded into polymer matrices, with possible applications in energy storing coatings. The NBD–QC photoswitches that are capable of absorbing sunlight with estimated solar energy storage efficiencies of up to 3.8% combined with attractive energy storage densities of up
Bis‐ and Tris‐norbornadienes with High Energy
Molecular solar thermal energy storage (MOST) systems can convert, store and release solar energy in chemical bonds, i.e., as chemical energy. In this work, phenyl- and naphthyl-linked bis- and tris-norbornadienes
Unraveling factors leading to efficient
Developing norbornadiene–quadricyclane (NBD–QC) systems for molecular solar-thermal (MOST) energy storage is often a process of trial and error. By studying a series of norbornadienes ( NBD-R 2 ) doubly substituted
Engineering of Norbornadiene/Quadricyclane
Solar thermal fuels (STFs) supply a closed cycle and renewable energy-storage strategy by transforming solar energy into chem. energy stored in the conformation of mol. isomers, such as cis/trans-azobenzene, and
Engineering of Norbornadiene/Quadricyclane Photoswitches for Molecular
ConspectusRenewable energy resources are mostly intermittent and not evenly distributed geographically; for this reason, the development of new technologies for energy
Solar Energy Storage by Molecular Norbornadiene
The NBD–QC photoswitches that are capable of absorbing sunlight with estimated solar energy storage efficiencies of up to 3.8% combined with attractive energy storage densities of up to 0.48 MJ kg −1.
Bis‐ and Tris‐norbornadienes with High Energy Densities for
Molecular solar thermal energy storage (MOST) systems can convert, store and release solar energy in chemical bonds, i.e., as chemical energy. In this work, phenyl- and naphthyl-linked bis- and tris-norbornadienes are presented as promising MOST systems with very high energy densities.
Norbornadiene-based photoswitches with exceptional combination of solar
Norbornadiene-quadricyclane (NBD-QC) photo-switches are candidates for applications in solar thermal energy storage. Functionally they rely on an intramolecular [2+2]
Two-way photoswitching norbornadiene derivatives for solar energy storage
Molecular photoswitches of norbornadiene (NBD) derivatives have been effectively applied in molecular solar-thermal energy storage (MOST) by photoisomerization of NBD to a quadricyclane (QC) state. However, a challenge of the NBD-based MOST system is the lack of a reversible two-way photoswitching process, limiting conversion from QC to thermal
Two-way photoswitching norbornadiene derivatives for solar energy storage
Molecular photoswitches of norbornadiene (NBD) derivatives have been effectively applied in molecular solar-thermal energy storage (MOST) by photoisomerization of NBD to a quadricyclane (QC) state. However, a challenge of the NBD-based MOST system is the lack of a reversible two-way photoswitching process, l
Monoaryl‐Substituted Norbornadiene Photoswitches as Molecular Solar
The energy storage densities are, as expected, lower than those of the parent norbornadiene (1 a). 12 This observation can be explained by the inverse correlation between
The Norbornadiene/Quadricyclane Pair as Molecular Solar Thermal Energy
In this review, we illustrated the evolution from the first discovery of the photoswitchable nature of norbornadiene as route for energy storage to the sophisticated molecular design of numerous derivatives with optimized properties.
Unraveling factors leading to efficient norbornadiene
Developing norbornadiene–quadricyclane (NBD–QC) systems for molecular solar-thermal (MOST) energy storage is often a process of trial and error. By studying a series of norbornadienes ( NBD-R 2 ) doubly substituted at the C7-position with R = H, Me, and iPr, we untangle the interrelated factors affecting MOST performance through a
Engineering of Norbornadiene/Quadricyclane Photoswitches for
Solar thermal fuels (STFs) supply a closed cycle and renewable energy-storage strategy by transforming solar energy into chem. energy stored in the conformation of mol. isomers, such as cis/trans-azobenzene, and releasing it as heat under various stimuli.
Front Cover: Push‐Pull Bis‐Norbornadienes for Solar
The norbornadiene derivatives designed and studied in this work swirl around the flask like autumn leaves symbolizing the cyclic nature of molecular solar thermal energy storage; and as leaves turn red in autumn, so
The Norbornadiene/Quadricyclane Pair as Molecular
In this review, we illustrated the evolution from the first discovery of the photoswitchable nature of norbornadiene as route for energy storage to the sophisticated molecular design of numerous derivatives with
Push-Pull Bis-Norbornadienes for Solar Thermal Energy Storage
A major challenge in the field of molecular solar thermal energy storage is designing visible light-absorbing photoswitches with long energy storage half-lives. Five novel visible light-absorbing norbornadiene dimers were prepared, with half-lives up to 23.0 hours, and high energy densities up to 379.3 kJ/kg.

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